In electrochemistry, a more reactive metal used to protect a less reactive metal from
corrosion. When the two metals are in close contact, the more reactive will always react first. For example,
zinc is used as a coating to protect steel (galvanization),
chromium electroplating is used for the protection of steel and other alloys, and
iron may be connected to magnesium or aluminium to prevent
rusting.
This protection is known as
sacrificial protection or
cathodic protection. A metal such as iron oxidizes because its atoms act as
anodes (positive electrodes) on contact with air or water, but if a more reactive metal is attached the iron atoms become
cathodes (negative electrodes) and the more reactive metal corrodes.
© RM 2009. Helicon Publishing is division of RM.