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After studying law in Spain and Belgium, in 1966 he opened the first labour-law office in his home city of Seville. In 1964 he joined the PSOE, and he rose rapidly to the position of leader. In 1982 the PSOE won a sweeping electoral victory and González became prime minister. Under his administration left-wing members of the PSOE, disenchanted with González's policies, formed a new party called Social Democracy in 1990. After his party's failure to retain an absolute majority in the 1989 parliamentary elections, González formed a coalition with Catalan and Basque nationalist parties, promising increased devolution to the country's regions.
The PSOE suffered, during the early 1990s, from a series of corruption scandals, and in 1995 González was accused of having been personally involved in the setting up of the Anti-terrorist Liberation Group, a paramilitary group that had been responsible for the deaths of scores of Basque separatists in the 1980s. A preliminary probe into the allegations was abandoned as a result of insufficient evidence, but the scandal cost him the support of his Catalan coalition partner.