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From 1896 the Curies worked together on radioactivity, building on the results of Wilhelm Röntgen (who had discovered X-rays) and Becquerel (who had discovered that similar rays are emitted by uranium salts). Marie Curie discovered that thorium emits radiation and found that the mineral pitchblende was even more radioactive than could be accounted for by any uranium and thorium content. In July 1898, the Curies announced the discovery of polonium, followed by the discovery of radium five months later. They eventually prepared 1 g/0.04 oz of pure radium chloride from 8 tonnes of waste pitchblende from Austria.
They also established that beta rays (now known to consist of electrons) are negatively charged particles. In 1910 with André Debierne (18741949), who had discovered actinium in pitchblende in 1899, Marie Curie isolated pure radium metal in 1911.